TlF - Pbcm

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1. Structure Summary

Last Updated

2022-12-09

Crystal Prototype

AB

Crystal System

Rectangular

Lattice Constant a (Å)

5.279

Lattice Constant b (Å)

5.802

Space Group

Pbcm

Formation Energy (eV/f.u.)

-4.6174

2. Mechanical Properties (PBE)

2.1 Stiffness Tensors

Cij (N/m)

xx

yy

zz

xx

18.065

7.070

0.000

yy

7.070

5.544

0.000

zz

0.000

0.000

5.769

2.2 Compliance Tensors

Sij (m/N)

xx

yy

zz

xx

0.110510

-0.140928

0.000000

yy

-0.140928

0.360094

0.000000

zz

0.000000

0.000000

0.173340

2.3 Orientation-Dependent Mechanical Properties

../_images/ELASTIC-TlF_Pbcm.png

2.4 Anisotropic Mechanical Properties Of 2D Singlecrystal

Mechanical Properties

Min

Max

Anisotropy

Young’s Modulus (N/m)

2.777

15.714

5.658

Shear Modulus (N/m)

1.329

5.769

4.341

Poisson’s Ratio

-0.043

1.275

-29.602

2.5 Anisotropic Mechanical Properties Of 2D Polycrystal

Mechanical Properties

Min

Max

Anisotropy

Young’s Modulus (N/m)

9.437

5.298

5.658

Shear Modulus (N/m)

4.068

2.160

4.341

3. Fundmental Electronic Properties

Band Character

Indirect

Band Gap (PBE, eV)

3.8635

Band Gap (HSE, eV)

4.8709

Ionization Energy (HSE, eV)

-6.502

Electron Affinity (HSE, eV)

-1.631

Effective Mass of Electron Max. (m0)

66.210

Effective Mass of Electron Min. (m0)

-7.752

Effective Mass of Hole Max. (m0)

6.676

Effective Mass of Hole Min. (m0)

0.628

Location of Valence Band Maximum

[0.400000, 0.400000]

Location of Conduction Band Minimum

[0.458333, 0.458333]

3.1 Global Band Structure (PBE)

../_images/3D_band-TlF_Pbcm.jpg

3.2 Band Structure and Density of States (PBE)

../_images/BAND_LDOS-TlF_Pbcm.png

3.3 Projected Band Structure and Density of States (PBE)

../_images/BAND_PDOS_Tl-TlF_Pbcm.png ../_images/BAND_PDOS_F-TlF_Pbcm.png

3.4 Orientation-Dependent effective Masses (PBE)

../_images/EMC-TlF_Pbcm.png

4. Optical Spectrums (HSE)

../_images/Optical-TlF_Pbcm.png

5. Phonon Spectrum and Density of States (PBE)

../_images/phonon_BAND_LDOS-TlF_Pbcm.png

References

Note

For more details of this database, please refer to the following reference.

[1] V. Wang, G. Tang, Y.-C. Liu, R.-T. Wang, H. Mizuseki, Y. Kawazeo, J. Nara, W.-T. Geng, High-Throughput Computational Screening of Two-Dimensional Semiconductors, Journal of Physical Chemistry Letters 13, 11581 (2022).

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